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It happened with me too. Luckily I was able to reinstate my account by sending a service request to Payoneer through the Help section. I believe you should do the same.
I have never come across such a case where Global payment service isn't available. Maybe your account isn't verified at the moment.
As far as i know, the card gets shipped everywhere. I also faced similar problem and then I found out that it was because of my address format that I wasn't able to receive my card. You have to be very careful while entering your home address.